:Abstract

This project includes and in deification the complexes of amino acid L-serine (serH) L-cysteine (cysH) , and L-threonin (thrH₂) with some ions of trace elements such as K₂ptCl₆ ,

Cu(NO₃)₂.3H₂O  , ZnCl₂ and HgCl₂ were studied by Infrared-spectra ‘NMR from this identification studies can give the structure formed for the complexes with were prepare with amino acids :

Na[pt(ser)Cl₄] .0.5C₂H₅OH   ,[Hg(ser)₂] .9H₂O , [Cu(ser)₂] , Na[pt(cys)₂Cl₃].0.5C₂H₅OH.3H₂O and

Keywords: metal complexes – Amino acids – Characterization .

الملخص:                                                                                                                                                              تم في هذا البحث تحضير وتشخيص بعض المعقدات من تفاعل بعض من ايونات العناصر هي : Z(II) , Cu(II) , Pt(IV) , Hg(II)    مع الأحماض الأمينية مثل السستايين و السيرين و الثرونين و التي شخصت بعدة طرق منها طيف الأشعة تحت الحمراء والمرئية وفوق البنفسجية بالأضافة الى استعمال الطرق الفيزيائية الأتية : درجة الأنصهار والذائيبية والتوصيل الكهربائي لمحاليلها .

الكلمات المفتاحية : الأحماض الأمينية – المعقدات – التشخيص

: Abstract

applications of complexes are very important in different sectors like the pharmaceutical industrial. So, this study aimed to preparation sodium salts of amino acids complexes by using K2PtCl6, Cu (NO3)2.3H2O, HgCl2 and ZnCl2 as a ligand reaction with the sodium salts of the following amino acids: glycine (glyH), L-alanine (alaH), L-phenylalanine (pheH). The following complexes were isolated: Na [Pt(gly)Cl4] .0.5C2H5OH, [Cu(ala)2].0.5C2H5OH, [Pt(ala)3Cl].C2H5OH.4H2O, [Pt(phe)2Cl2].0.5C2H5OH.1.5H2O, [Hg(phe)2].9H2O, [Zn(phe)2].C2H5OH. The isolated complexes have been characterized by their elemental analysis’s solubility, conductivity measurements, IR, electronic absorption and C13 NMR spectra.

Keywords: Metal complexes, Amino acids, Characterization.

الملخص:

تطبيقات المعقدات مهمة جد ا في مجاالت مختلفة مثل الصناعات الدوائية، عليه است هدفت هذه الدراسة تح ضير معقدات أمالح الصوديوم أمالح مع الليكاندات كتفاعالت K2PtCl6, Cu (NO3)2.3H2O, HgCl2 and ZnCl2 معقدات بواسطة الصوديوم لألحماض األميني ة التالية: الجاليسي ين (glyH(، L- أالنين (alaH(، L- فينيل أالنين )pheH). وت م الحصول على ست معقدات مختلفة: Na [Pt(gly)Cl4] .0.5C2H5OH, [Cu(ala)2].0.5C2H5OH, [Pt(ala)3Cl].C2H5OH.4H2O, [Pt(phe)2Cl2].0.5C2H5OH.1.5H2O, [Hg(phe)2].9H2O, [Zn(phe)2].C2H5OH تم تشخيص هذه المركبات عن طريق تحليل العناصر المكونة لها وايجاد نسبتها باإلضافة إلى استعمال الطرق الفيزيائ ية األتية: درجة االنصهار، الذائ ب ية، التوصيل الكهربائي لمحاليلها، واألطي اف تحت الحمراء والمرئية وفوق البنفسجية إلى الرنين المغناطيسي.

الكلمات المفتاحية: المعقدات، األحماض األمينية، التشخيص.

The study aimed to present the first record of insect families in Farwa Island. Farwa Island is the largest and most important island in Libya; located in Northern west part of Libya in the Mediterranean, its insect fauna is poorly studied. Short time intensive collection of insect samples was conducted in four areas (mouth of the valley, bay of containers, center of the Island, and Ras-Attalgha) in February, March and April 2021. Different methods were used for insect collection, sorting, preservation and later identification to the lowest taxonomic level and verification. 9 orders, 31 families, 40 genera and 58 insect species were collected in the study; the center of the Island had the highest numerical density and diversity of insect fauna due to its diverse vegetation compared to other areas. Diverse suitable habitats and absent insect control measures provided suitable environmental conditions for insects breeding, feeding and hiding from enemies. This study constitutes the first comprehensive survey of insect fauna on Farwa Island and adds significant value to the ongoing assessment of insect diversity in Libya. A long-term study has to be conducted to investigate detailed information about the abundance and diversity of insects and other arthropods on Farwa Island.

The United States (US) as the second leading economy in global ecological pollution has become a fertile ground for a rigorous analysis of the ecological neutrality using load capacity factor (LCF) and carbon-based consumption (CCO2). This is important for the global drive of achieving environmental sustainability by 2050. The LCF is one of the most comprehensive ecological proxies that incorporate the biocapacity and ecological footprint. In this context, this research examines the effect of natural resources, technological innovation, renewable energy and financial globalization on ecological neutrality in the US for the date spanning from 1990 to 2021. Using the novel augmented auto-regressive distributive lag (AARDL) model, the empirical findings of this study indicate that (i) natural resources, renewable energy, and technological innovation promote ecological neutrality by increasing LCF and decreasing CCO2 emissions; (ii) financial globalization and economic growth mitigate the LCF and increase CCO2 emissions; and (iii) a causal effect is observed among technological innovation, natural resources, renewable energy, CCO2 and LCF. In light of the findings, this study recommends several crucial measures for ecological neutrality targets set out in sustainable development goals (SDGs) 7 and 13, respectively.

Heavy metals can be released from cooking stewpots into food, causing food contamination and posing a risk to human health. This research study investigated the release of heavy metals into food from stewpot cookers used in Gharyan, Libya. As well as, investigating the effect of scratches, acidic food, and storage on the concentrations of those metals. Eight new and used cooking stewpots (with scratches) made of: (Tefal, stainless steel, copper and aluminum) were collected, and then fresh tomato juice was cooked in these stewpots and left in the refrigerator for six days, the samples were digested and analyzed by atomic absorption spectrophotometer (AAS) to measure the concentration of the heavy metals: (cadmium, lead, iron, copper and zinc). Results showed that cadmium and lead concentrations were less than the detection limit of the AAS instrument, except for one sample (old Tefal stewpot with scratches), in which the lead concentration was (0.046ppm). The concentration of iron, copper and zinc in the samples was less than the maximum limit allowed by WHO/FAO; except for one sample in which the iron concentration exceeded that value (old copper pot with scratches) and its value was (2.892ppm). The results of the descriptive statistical analysis showed that the average concentration of iron (0.493 ppm) was higher than that of zinc and copper (0.054 ppm), (0.016 ppm), respectively. In addition, the rate of leakage of those elements from old (scratched) cookware was higher than that from the new ones made from the same material, and the concentration of these elements increases significantly when these stewpots contain scratches, since that increases the rate of leakage of those metals, especially in acidic food such as tomatoes.

The genus Segestria Latreille, 1804 and the species Segestria florentina (Rossi, 1790) are recorded in Libya for the first time, based on a single adult female specimen

Abstract

Seven male specimens (one immature and six adults) of a rare species of Loureedia jerbae (El-Hennawy, 2005), are recorded for the first time in Libya, representing the first record of this species outside of Tunisia. Illustrations and a description are provided. Only the most recent adult of the specimens captured in October/November of 2019 to 2022 was examined, identified and described. Although Libya has one of the least recorded spider species in the Mediterranean region, it is promising to reveal more undiscovered and undocumented species through extensive research in this large country

In this paper, we introduced two novel subclasses of bi-univalent functions, Με (α, Β(α, ξ)) and ΗΣ (α, μ, Β(x, ξ)), utilizing Lucas-Balancing polynomials. Within these function classes, we established bounds for the Taylor-Maclaurin coefficients |a2| and a3, addressing the Fekete-Szegö functional problems specific to functions within these new subclasses. Moreover, we illustrated how our primary findings could lead to various new outcomes through parameter specialization.

Abstract

The research was conducted to discuss the impact of Derna floods on children’s education and their mental and psychological state, and emergency measures to confront the disaster. It has explained and talked about the tragedy that happened in Derna and other eastern cities. Furthermore, it has been mentioned the coping mechanism for schools. In addition, this research has been mentioned the impacts of storm Daniel on Derna. And, it has been discussed the effective steps to rebuild education facilities in the affected areas. Besides, it has been explained how to help children who have been affected by floods, which must have been awared by parents and caregivers. Finally, it has been explained the impact of trauma on children and some important tips for the sectors on how to be better support children and young people affected by flooding.

The battle against COVID-19 does not always end when recovery is declared. Many individuals confirmed recovered from COVID-19 continue to experience a variety of symptoms. The aim of this study was to shed more light on COVID-19 and post-COVID-19 symptoms in Libya. Two hundred and twenty Libyan individuals (58% female; 42% male), who recovered from COVID‐19, were asked to answer a questionnaire that was performed to inquire about the presence of COVID-19 and post-COVID-19 symptoms. Additionally, comorbidities and demographic data were included. The most common comorbidities were hypertension (20%), diabetes (16%), and lung disease (08%). The main COVID-19 symptoms were headache (56%), anosmia and ageusia (52%), Arthralgia (48%), cough (46%) and fever (41%). While the post-COVID-19 symptoms were fatigue (64%), sleep disorders (52%), insomnia, anxiety, depression (42%), and anosmia and ageusia (32%). Persistent COVID and its related long-term complications may continue to affect patients and their families.