Abstract:

This study assesses the implementation level of the Occupational Health and Safety Management System (OHSMS) based on ISO 45001:2018 at Brega Oil Marketing Company (BOMC), Libya. A quantitative descriptive methodology was employed using a structured questionnaire derived from ISO 45001 clauses. Data were collected from 60 employees across four operational sites and analyzed using descriptive statistics in IBM SPSS. The results indicate partial compliance with ISO 45001 requirements (mean ≈ 3.82). Strong performance was observed in safety awareness and employee satisfaction, whereas weaknesses were identified in planning, hazard identification, and performance evaluation processes. The study recommends strengthening risk-based planning and internal auditing mechanisms to improve system effectiveness and ensure continual improvement.

Keywords: Occupational Health and Safety, ISO 45001, Gap Analysis, Oil and Gas Industry, Brega Oil Marketing Company. 

Polyvinylpyrrolidone (PVP; poly(N-vinylpyrrolidone)) is a versatile water-soluble polymer widely used in pharmaceuticals, coatings, and nanocomposites due to its solubility, biocompatibility, and film-forming properties. Despite its extensive applications, systematic kinetic data describing its thermal degradation remain limited. In this study, non-isothermal thermogravimetric analysis (TGA) of PVP was performed under nitrogen and air atmospheres at heating rates of 5, 10, 20, and 40 °C min⁻¹. Thermal profiles revealed three degradation stages: moisture loss (30–150 °C), main-chain scission and depolymerization (150–450 °C), and carbonaceous residue formation (>450 °C), with the principal decomposition peak at 370–410 °C. Activation energies (Eₐ) determined using Kissinger, Flynn–Wall–Ozawa (FWO), and Kissinger–Akahira–Sunose (KAS) methods ranged from 179 to 186 kJ mol⁻¹ and were validated using the Coats–Redfern model-fitting approach. Reaction orders (n ≈ 1.1–1.3) indicate random chain scission as the dominant mechanism. The resulting kinetic dataset provides reliable insight into PVP thermal stability and supports optimization of processing, recycling, and composite fabrication.

Abstract:

This study aimed to compare the amount of stress generated on two versus four implants with equator attachments in maxillary implant overdentures with palatal coverage and palateless designs. Four standardized educational edentulous maxillary models simulating bone type II were used. The models were divided into two main groups according to palatal design (palatal coverage and palateless), and each group was further subdivided based on the number of implants (two or four implants). In the two-implant subgroup, implants were placed bilaterally in the canine regions perpendicular to the residual ridge using a surgical stent, whereas in the four-implant subgroup, implants were installed bilaterally in the canine and second premolar regions. Equator attachments with appropriate cuff heights were selected, and framework patterns were constructed. Four strain gauges were cemented to each fixture using strain gauge cement. A LLOYD digital loading device was used to apply compressive loads to measure the resulting stresses around the implants for each attachment configuration. The results demonstrated a statistically significant difference between stresses on two implants with equator attachments (74.53 ± 35.9 N/m × 10²) and four implants with equator attachments (10.85 ± 10.81 N/m × 10²) within the same palatal coverage design. Similarly, a statistically significant difference was found between stresses on two implants with equator attachments (123.75 ± 44.60 N/m × 10²) and four implants with equator attachments (14.51 ± 14.60 N/m × 10²) within the same palateless design. It was concluded that stress on two implants with equator attachments was markedly greater in the palateless design compared with the palatal coverage design, whereas stress on four implants with equator attachments was slightly greater in the palateless design than in the palatal coverage design, with no statistically significant difference.

Abstract:

This study aimed to evaluate stress distribution around two and four implants supporting maxillary implant overdentures retained by locator attachments, comparing full and partial palatal coverage designs. Four identical acrylic models representing completely edentulous maxillary arches were fabricated and covered with polyvinyl siloxane impression material to simulate the oral mucosa overlying the residual ridge. The models were divided into two main groups according to the number of installed implants (two or four), and each group was further subdivided based on palatal design (full or partial palatal coverage). Locator abutments (female components) were secured to the implants using an abutment driver, after which the prosthetic frameworks were constructed. Four strain gauges were bonded to each implant fixture using strain gauge cement to record strain values. A LLOYD digital loading device was employed to apply controlled compressive loads, and the resulting stresses around the implants were measured for each configuration.

Statistical analysis revealed a significant difference in stress values between two-implant overdentures with full palatal coverage (30.64 ± 17.47 N/m × 10²) and those with partial palatal coverage (49.72 ± 23.17 N/m × 10²), with higher stresses observed in the partial coverage design. In contrast, although four-implant overdentures with partial palatal coverage (8.77 ± 4.54 N/m × 10²) demonstrated higher mean stress values than those with full palatal coverage (5.51 ± 3.83 N/m × 10²), this difference was not statistically significant.

Within the limitations of this in vitro study, full palatal coverage design resulted in lower stress values compared to partial palatal coverage in two-implant-supported maxillary overdentures. For four-implant-supported overdentures, full palatal coverage also showed lower stress values; however, the difference was not statistically significant.

This study compared the retention of polyamide clasps engaging porcelain-fused-to-metal and zirconia retainers with identical 0.50 mm undercuts in posterior free-end saddle maxillary removable partial dentures. Four standardized acrylic resin models simulating maxillary bilateral posterior edentulous with first premolar abutments were prepared to receive either porcelain-fused-to-metal or zirconia crowns incorporating mesial occlusal rest seats. Polyamide RPA clasps were fabricated using an injection molding technique and tested for retention using a universal testing machine at a crosshead speed of 5 mm/min. The mean retention force of polyamide clasps was 6.68 ± 2.59 N for zirconia crowns and 5.47 ± 2.27 N for porcelain-fused-to-metal crowns. The results demonstrated minimal loss of retention for polyamide clasps against both ceramic materials, with no significant difference in retention related to the type of ceramic retainer.